Product ID:NP-4835 TONER BLACK
MSDS Date:12/01/1995
FSC:6850
NIIN:01-409-0947
MSDS Number: CJHDD

Emergency Phone: 516-328-5600

Info Phone: 516-328-5600

Cage: 08YZ7

Telephone: 716-633-0361

Cage: 0VZV9

STYRENE ACRYLATE COPOLYMER

IRON OXIDE

CAS: 1317-61-9

OSHA PEL 10 MG/M3

ACGIH TLV: 5 MG/M3

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:SKIN/INHALED/INGESTED: LOW HAZARD FOR
RECOMMENDED HANDLING. EYES-NO SPECIFIC HAZARDS KNOWN. MAY CAUSE
TRANSIENT IRRITATION.
Explanation of Carcinogenicity:CARCINOGENICITY CLASSIFICATION
(COMPONENTS PRESENT AT 0.1% OR MORE) : NONE.
Effects of Overexposure:NONE SPECIFIED BY MANUFACTURER.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHALATION-IF SYMPTOMATIC, REMOVE FROM EXPOSURE TO FRESH AIR.
GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES- ANY MATERIAL THAT
CONTACT THE EYES SHOULD BE WASHED OUT IMMEDIATELY. GET MEDICAL
ATTENTIO N IF SYMPTOMS PERSIST. SKIN- WASH WITHSOAP AND WATER. GET
MEDICAL ATTENTION IF SYMPTOMS PERSIST. INGESTION- DRINK SEVERAL
GLASSES OF WATER. SEEK MEDICAL ATTENTION.

Flash Point:NON-FLAMMABLE
Extinguishing Media:WATER SPRAY,CARBON DIOXIDE (CO2), DRY CHEMICALS.
PRODUCT IS NON-FLAMMABLE SOLID (ACCORDING TO TEST METHOD OF 16 CFR
1500.44).
Fire Fighting Procedures:NONE.
Unusual Fire/Explosion Hazard:TONER MATERIAL, LIKE MOST ORGANIC
MATERIAL IN POWDER FORM, IS CAPABLE OF CREATING A DUST EXPLOSION.

Spill Release Procedures:SWEEP MATERIAL ONTO PAPER AND PLACE IN FIBER
CARTON. DO NOT USE A VACUUM CLEANER TO CLEAN UP SPILLS OF POWDERED
TONER. THE FINE PARTICLES CAN CAUSE A FIRE OR EXPLOSION.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP OUT OF REACH OF CHILDREN. KEEP
FROM CONTACT WITH OXIDIZING MATERIALS. MINIMIZE DUST GENERATION AND
ACCUMULATION. KEEP CONTAINER CLOSED. USE ADEQUATE VENTILATION.
Other Precautions:REFER TO PAMPHLET NO. 654, "PREVENTION OF FIRE AND
DUST EXPLOSIONS IN THE CHEMICAL, DYE, PHARMACEUTICAL AND PLASTICS
INDUSTRIES."

Respiratory Protection:NONESHOULD BE NEEDED.
Ventilation:GOOD VENTILATION (TYPICALLY 4-6 ROOM VOLUMES PER HR) SHOULD
BE USED.VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS.
Protective Gloves:IMPERVIOUS GLOVES SHOULD BE WORN.
Eye Protection:IT IS GOOD INDUSTRIAL HYGIENE PRACTICE TO MINIMIZE EYE
CONTACT.
Other Protective Equipment:RERCOMMENDED DECONTAMINATION FACILITIES:
WASHING FACILITIES.
Work Hygienic Practices:GOOD INDUSTRIAL HYGIENE PRACTICES SHOULD BE
FOLLOWED WHICH INCLUDES PREVENTING EYE CONTACT, MINIMIZING SKIN
CONTACT, INHALATION. WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.

HCC:N1
Melt/Freeze Pt:M.P/F.P Text:100-150C
Spec Gravity:1.4~1.6 (WATER=1)
Evaporation Rate & Reference:N/A (N-BUTYL ACET)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:SOLID FINE POWDER,BLACK, WITH SLIGHT PLASTIC
ODOR.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:COMBUSTION WILL PRODUCE CARBON
DIOXIDE AND POSSIBLY TOXIC CHEMICALS SUCH AS CARBON MONOXIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:INCINCERATE OR LANDFILL. CAN BE INCINERATED WHEN
IN COMPLIANCE WITH LOCAL REGULATIONS. DISCHARGE, TREATMENT OR
DISPOSAL MAY BE SUBJECT TO FEDERAL, STATE OR LOCAL LAWS.

Toxicological Information:HEALTH HAZARDS OF LONG TERM EXPOSURE
(CHRONIC): BASED UPON AVAILABLE DATA, HUMAN EXPOSURE TO TONER HAS
BEEN SHOWN TO CAUSE MINIMAL RESPIRATORY TRACT IRRITATION AS MAY
OCCUR WITH LARGE AMOUNTS OF ANY N ONTOXIC DUSTS. THE RESULTS OF ONE
ANIMAL STUDY WHERE RATS INHALAED TONER THAT WAS TEN TIMES MORE
RESPIRABLE THAN COMMERCIALLY AVAILABLE TONER WERE OBSERVED TO HAVE
NO LUNG CHANGES AT LOW EXPOSURES. AT HIGHER LEVELS A SLIGHT DEGREE
OF LUNG FIBROSIS WAS OBSERVED DUE TO EXCESSIVEAMOUNTS OF DUST
RETAINED I THE LUNGS FOR A PROLONGED INTERVAL.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:THIS MATERIAL HAS NOT BEEN TESTED FOR ENVIRONEMENTAL
EFFECTS. IN A SPILL SITUATION THIS MATERIAL MAY BE VISUALLY
UNPLEASANT; HOWEVER, IT IS NOT EXPECTED TO CAUSE ANY ADVERSE
ENVIRONMENTAL EFFECTS.

Transport Information:SHIPPING NAME: NOT REGULATED.

SARA Title III Information:CHEMICALS SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OR TITLE III OF THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT (SARA) OF 1986 AND 40 CFR 372:
NONE.
Federal Regulatory Information:RCRA STATUS: IF DISCARDED IN ITS
PURCHASED FORM, THIS PRODUCT WOULD NOT BE A HAZARDOUS MATERIAL
EITHER BY LISTING OR BY CHARATERISTIC. HOWEVER, UNDER RCRA, IT IS
THE RESPONSIBILITY OF THE END-USER TO DETERMINE AT THE TIME OF
DISPOSAL, WHETHER A MATERIAL A MATERIAL CONTAINING THE PRODUCT OR
DERIVED FROM THE PRODUCT SHOULD BE CLASSIFIED AS HAZARDOUS WASTE;
40 CFR 261.20-24. TSCA STATUS:ALL CHEMICAL INGREDIENTS FOUND ON
TSCA INVENTORY.
State Regulatory Information:MATERIALS KNOWN TO THE STATE OF CALIFORNIA
TO CAUSE CANCER: NONE. MATERIALS KNOWN TO THE STATE OF CALIFORNIA
TO CAUSE HARMFUL REPRODUCTIVE EFFECTS: NONE.